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Research team discovers two-dimensional waveguides

NRL discovers two-dimensional waveguides
Real-space (left) and Fourier space (right) photoluminescence image of a hexagonal boron nitride waveguide. The real-space image shows where photoluminescence is emitted from within the sample, while the Fourier space image depicts the angle of the emitted light. Image taken by Nicholas Proscia in April 2023. Credit: U.S. Naval Research Laboratory/Nicholas Proscia

The U.S. Naval Research Laboratory (NRL), in collaboration with Kansas State University, has discovered slab waveguides based on the two-dimensional material hexagonal boron nitride. This milestone has been reported in the journal Advanced Materials.

Two-dimensional (2D) materials are a class of materials that can be reduced to the monolayer limit by mechanically peeling the layers apart. The weak interlayer attractions (van der Waals attraction) allow the layers to be separated via the so-called "Scotch tape" method.

The most well-known 2D material, graphene, is a semimetallic material consisting of a single layer of carbon atoms. Recently, other 2D materials including semiconducting (TMDs) and insulating hexagonal boron nitride (hBN) have also garnered attention. When reduced near the monolayer limit, 2D materials have unique nanoscale properties that are appealing for creating atomically thin electronic and .

"We knew using would lead to outstanding optical properties in our samples; none of us expected that it would also act a ," said Samuel Lagasse, Ph.D., Novel Materials and Applications Division. "Since hBN is used so widely in 2D material–based devices, this novel usage as an optical waveguide potentially has wide-ranging impacts."

Graphene and TMD monolayers are both extremely sensitive to the surrounding environment. Therefore, researchers have sought to protect these materials by encapsulating them in a passivating layer. This is where hBN comes in: layers of hBN are able to "screen" impurities near graphene or TMD layers, leading to fantastic properties. In recent NRL-led work, the thickness of hBN surrounding a light-emitting TMD layer was carefully tuned in order to support optical waveguide modes.

Researchers at NRL carefully assembled stacks of 2D materials known as "van der Waals heterostructures." These heterostructures can have specialized properties due to the layering. Slabs of hBN were placed around single layers of TMDs, such as molybdenum diselenide or tungsten diselenide, which can emit light in the visible and near-infrared.

The slabs of hBN were carefully tuned in thickness so that the emitted light would be trapped within the hBN and waveguided. When the light waveguides to the edge of the hBN, it can scatter out and be detected by a microscope.

The research was motivated by the challenges of optical measurements of 2D TMDs. When is focused on TMDs, particles known as excitons are generated. Most excitons emit light out of the plane of the TMD; however, an elusive type of exciton known as a dark exciton exists in some TMDs, and emits in the plane of the TMD. NRL's slab waveguides capture the light from the dark excitons, providing a way to study them optically.

NRL discovers two-dimensional waveguides
Confocal microscope image of waveguided photoluminescence in a hexagonal boron nitride waveguide. The lobe-pattern around the edges is reminiscent of koi circling a pond. Image taken by Samuel LaGasse in April 2023. Credit: U.S. Naval Research Laboratory/Samuel LaGasse

"2D materials have exotic optoelectronic properties that will be useful to the Navy," said Lagasse. "A large challenge is interfacing these materials with existing platforms without damaging them—these boron nitride waveguides are a step towards that realization."

NRL researchers used two special types of optical microscopes to characterize the hBN waveguides. One setup allows researchers to spectroscopically resolve photoluminescence emitting from different spots of the waveguide. The other setup lets them observe the angular distribution of the emitted light.

The NRL researchers also developed 3D electromagnetic models of the waveguides. The modeling results provide a tool kit for designing future 2D devices that use slab waveguides.

More information: Samuel W. LaGasse et al, Hexagonal Boron Nitride Slab Waveguides for Enhanced Spectroscopy of Encapsulated 2D Materials, Advanced Materials (2023). DOI: 10.1002/adma.202309777

Citation: Research team discovers two-dimensional waveguides (2024, February 15) retrieved 7 March 2024 from https://phys.org/news/2024-02-team-dimensional-waveguides.html
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